The four six set will include music from across the series. Each disc is themed:
- Disc one features music by Dennis McCarthy, with cues from many episodes, including "Duet", "The Circle", "The Die is Cast", and "Far Beyond the Stars".
- Disc two focuses on the music of Jay Chattaway, including cues from "The Search", "Call to Arms", "The Changing Face of Evil", and more.
- Disc three, titled "New Recruits" focuses on the many guest composers that contributed to the series, with music by John Debney, Richard Bellis, David Bell, Gregory Smith, and Paul Baillargeon.
- Disc four, called "The Lost Album", will give more extensive coverage to just three episodes, one of which will be "Our Man Bashir".